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Sodium persulfate

  

Sodium persulfate

Other names

sodium peroxodisulfate
sodium peroxodisulphate
sodium peroxydisulfate
sodium peroxydisulphate

Identifiers

CAS number

7775-27-1

EINECS number

[231-892-1 [231-892-1]]

Properties

Molecular formula

Na 2 S 2 O 8

Molar mass

238.03 g/mol

Appearance

white powder

Melting point

180°C (decomposes)

Solubility in water

700 g/L (20°C)

Acidity (p K a )

6.0 (1% solution)

Hazards

EU classification

not listed

 

 

R-phrases

R8 R20 R22 R36 R37 R38 R42 R43

S-phrases

S8 S17 S26 S36

 

Sodium persulfate ( Na 2 S 2 O 8 ) is a chemical compound . It is a strong oxidizer . It is a severe irritant of skin, eyes, and respiratory system. It is almost non- hygroscopic and has particularly good ability to be stored for long time. It is easy and safe to handle. It is not combustible, but releases oxygen easily and assists combustion of other materials.

It is used as a bleach , both standalone (particularly in hair cosmetics) and as a detergent component. It is a replacement for ammonium persulfate in etching mixtures for zinc and printed circuit boards , and is used for pickling of copper and some other metals. It is a source of free radicals , making it useful as a radical initiator for emulsion polymerization reactions and for accelerated curing of low formaldehyde adhesives. It is also used as a soil conditioner and in manufacture of dyestuffs , modification of starch , bleach activator, desizing agent for oxidative desizing, etc.

Conditions/substances to avoid mixing persulfates with are: moisture , heat , flame , ignition sources, shock , friction , reducing agents , organic material, sodium peroxide , water , aluminium and powdered metals.

Sodium persulfate is a oxidizing agent in chemistry , for example in a synthesis of diapocynin from apocynin where iron(II) sulfate is the radical initiator [1] :

Diapocynin Synthesis

The sulfate radical formed in situ has a standard electrode potential of 2.7V.

   
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Last Update:Oct 18,2008